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矿冶:2023,32(4):-
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粒化铜渣余热回收与气基直接还原技术研究
史彦辉1, 武海军1, 杨国强1, 张娟2, 张晓冬3, 段东平3
(1.赤峰白音华物流有限公司;2.上海发电设备成套设计研究院有限责任公司;3.中国科学院过程工程研究所)
Study on the Technology of Waste Heat Recovery and Gas-based Direct Reduction of Granulated Copper Slag
Shi Yanhui1, Wu Haijun1, Yang Guoqiang1, zhangjuan2, zhangxiaodong3, duandongping3
(1.Chifeng Baiyinhua Logistics Co., Ltd;2.Shanghai Power Equipment Research Institute Co., Ltd;3.Institute of Process Engineering, Chinese Academy of Sciences)
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本文已被:浏览 756次   下载 518
投稿时间:2022-12-15    修订日期:2023-03-06
中文摘要: 火法炼铜过程中产生大量的液态高温渣,一般通过缓冷水淬方式冷却,该处理过程时间长、耗水量大,造成大量的高质热量散失。为提高冶炼铜渣的处理效率和余热利用率,兼顾有价金属元素的回收利用,本文提出转杯粒化技术、颗粒流储换热余热发电技术和气基直接还原铜渣技术结合的工艺系统,并基于此工艺流程进行了物质流、能量流分析。本工艺利用了颗粒流在换热、化学反应过程中的高换热面密度和流动性,通过转杯粒化将液态铜渣转化为流动性好的高温粒化铜渣,分别经过颗粒流换热和气基直接还原回收铜渣中的高温余热和有价金属,可实现铜渣连续化处理工艺,占地小、无水耗,降低了铜冶炼工艺能耗和环保成本。本工艺系统中,每处理1 t铜渣,可回收海绵铁431 kg,余热发电95 kWh,铜渣总余热的77.5%得到回收利用。
Abstract:This paper studies a process system combining rotating cup granulation technology, particle flow heat transfer and exchange technology and gas-based direct reduction technology. The purpose of this system is to improve copper slag treatment efficiency and waste heat utilization rate. Material flow and energy flow of the process system are established. The system makes use of the advantages of particle flow, for instance high areal density and flowability in heat exchange and chemical reaction process. In the process system, liquid copper slag with high temperature is granulated into slag particles in dry granulation techniques, and the heat and valuable metals are recovered in particle flow heat transfer and gas-based direct reduction process modules which followed, respectively. Under the working condition designed in this paper, the copper slag can be treated continuously and instantly, which could reduce energy consumption and environmental cost of copper smelting process. It has the advantages of less space and no water consumption, compared with the slow-cooling process. The results of this study indicate that 431 kg sponge iron will be recovered for every ton of copper slag, in the meantime 77.5% of the total heat in slag will be recycling which can be reused for power generation 95 kWh.
文章编号:20221215002     中图分类号:    文献标志码:
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史彦辉,武海军,杨国强,张娟,张晓冬,段东平.粒化铜渣余热回收与气基直接还原技术研究[J].矿冶,2023,32(4):.

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