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矿冶:2023,32(4):-
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滇池地区磷块岩中倍半氧化物的赋存状态研究
庞建涛1, 李树建2,1, 肖喆2,1, 杨建光2,1, 袁明礼2,1, 丁文俊2,1, 吴浩2,3
(1.云南磷化集团有限公司;2.国家磷资源开发利用工程技术研究中心;3.中国矿业大学矿业工程学院)
Study on the Occurrence State of Sesquioxide in Phosphorite in Dianchi Area
PANG Jian-tao1, LI shu-jian.2,1, XIAO zhe2,1, YANG jian-guang2,1, YUAN ming-li2,1, DING wen-jun2,1, WU hao.2,3
(1.Yunnan Phosphating Group Co,Ltd;2.National Phosphorus Resources Development and Utilization Engineering Research Center;3.School of Mining Engineering,China University of Mining and Technology)
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投稿时间:2023-05-15    修订日期:2023-05-25
中文摘要: 为了降低磷矿精矿中的倍半氧化物含量,提高湿法磷酸品质,利用XRF、偏光显微镜、SEM、MLA等技术手段,查明了磷矿矿物组成特征、倍半氧化物的赋存特征、磨矿分异特征、赋存矿物单体解离特征等。研究结果表明:Fe2O3主要赋存在褐铁矿中,主要呈集合体形式集中分布、星点状分散分布、侵染状分布、脉状分布;Al2O3主要赋存在白云母、水云母中,呈碎片状,为层状硅酸盐矿物。磨矿后Fe2O3、Al2O3均有向细粒级富集的分异特征,且单体解离情况较好,为选矿脱除提供了基础条件。褐铁矿和层状硅酸盐矿物表面具亲水性,磷矿反浮选工艺难以脱除。
Abstract:In order to reduce the content of sesquioxide in phosphate ore concentrate and improve the quality of wet process phosphoric acid, XRF, polarizing microscope, SEM, MLA and other technical means were used to identify the mineral composition characteristics of phosphate ore, the occurrence characteristics of sesquioxide, grinding differentiation characteristics, and the dissociation characteristics of the host mineral monomer. The research results show that Fe2O3 mainly exists in limonite, mainly in the form of aggregation, star point dispersion, infection and vein distribution; Al2O3 is mainly hosted in muscovite and hydromica, in the form of fragments, and is a layered silicate mineral. After grinding, both Fe2O3 and Al2O3 exhibit differentiation characteristics towards fine-grained enrichment, and the monomer dissociation is good, providing a basic condition for mineral processing and removal. The surface of limonite and layered silicate minerals is hydrophilic, and it is difficult to remove phosphate rock by reverse flotation process.
文章编号:20230515001     中图分类号:    文献标志码:
基金项目:国家自然科学基金(52204160);中国博士后科学基金(2022MD713814)
引用文本:
庞建涛,李树建,肖喆,杨建光,袁明礼,丁文俊,吴浩.滇池地区磷块岩中倍半氧化物的赋存状态研究[J].矿冶,2023,32(4):.

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