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矿冶:2025,34(1):-
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四川某白钨矿加温浮选试验研究
李悦1, 谢贤1, 周凌志2, 吴雨瑶2, 王翔2, 李加文2, 张守逊2
(1.昆明理工大学 国土资源工程学院;2.昆明理工大学)
Experimental Study on Heating Flotation of a Scheelite Ore in Sichuan Province
LI Yue1, XIE Xian1, Zhou lingzhi2, wu yu yao2, wang xiang2, li jia wen2, zhang shou xun2
(1.Kunming University of Science and Technology,School of Land and Resources Engineering,Kunming;2.kunming university of science and technology)
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投稿时间:2024-01-03    修订日期:2024-01-18
中文摘要: 来自四川省的某钨矿含WO3 0.50%,含Cu 0.17%,含S 2.14%。该矿石中钨全部以独立矿物的形式赋存于白钨矿中,白钨矿是主要回收的金属矿物,其次是黄铜矿。针对该矿石中白钨矿及脉石矿物的组成及嵌布特性,采用“硫化矿浮选-白钨常温粗选-白钨加温精选”的原则流程,开展了碳酸钠用量、水玻璃用量、捕收剂种类及用量、加温氢氧化钠用量、加温水玻璃用量条件试验研究。试验结果表明,ZL捕收剂能提高白钨矿表面的疏水性,具有较强的捕收能力和较好选择性;采用加温精选的方法,能够有效抑制含钙脉石矿物,实现白钨矿与含钙脉石的有效分离。在最佳药剂制度的基础上,开展了“一粗一扫四精一精扫”的闭路试验,获得了WO3品位60.45%、回收率86.46%的白钨精矿,实现了对白钨矿的有效回收。
中文关键词: 白钨矿  加温浮选  ZL捕收剂
Abstract:A tungsten ore from Sichuan Province contains WO3 0.50 %, Cu 0.17 % and S 2.14 %. Tungsten in the ore is all present in the form of independent minerals in scheelite. Scheelite is the main recovered metal mineral, followed by chalcopyrite. According to the composition and dissemination characteristics of scheelite and gangue minerals in the ore, the principle process of " sulfide ore flotation-scheelite roughing at room temperature-scheelite heating cleaning " was adopted. The experimental study on the conditions of sodium carbonate dosage, water glass dosage, collector type and dosage, heating sodium hydroxide dosage and heating water glass dosage was carried out. The experimental results show that ZL collector can improve the hydrophobicity of scheelite surface, and has strong collecting ability and good selectivity. The method of heating concentration can effectively inhibit the calcium-containing gangue minerals and realize the effective separation of scheelite and calcium-containing gangue. On the basis of the best reagent system, the closed-circuit test of " one roughing, one scavenging, four cleaning and one cleaning " was carried out, and the scheelite concentrate with WO3 grade of 60.45 % and recovery rate of 86.46 % was obtained, which realized the effective recovery of scheelite.
文章编号:20240103001     中图分类号:P579;TD923;TD913    文献标志码:
基金项目:国家自然科学(编号:52174252)
引用文本:
李悦,谢贤,周凌志,吴雨瑶,王翔,李加文,张守逊.四川某白钨矿加温浮选试验研究[J].矿冶,2025,34(1):.

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