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矿冶:2025,34(1):-
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受巯基乙酸钠抑制的铜锌硫硫化矿可浮性规律研究
代旺1, 邓荣东1, 肖世洁1, 赵睿祺1, 李鑫2
(1.福州大学紫金地质与矿业学院;2.中国冶金地质总局第二地质勘查院)
Study on the floatability law of copper-zinc sulfide ore inhibited by sodium thioglycolate
DAI WANG1, DENG RONGDONG1, XIAO SHIJIE1, ZHAO RUIQI1, LI XIN2
(1.Zijin College of Geology and Mining, Fuzhou University;2.The Second Geological Exploration Institute, China Metallurgical Geology Bureau)
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投稿时间:2024-02-09    修订日期:2024-03-18
中文摘要: 针对受巯基乙酸钠抑制后的铜锌硫硫化矿难以分离回收的问题,本文通过纯矿物试验探究了丁基黄药、硫酸铜和双氧水对受巯基乙酸钠抑制后这些硫化矿的可浮性规律及相关机理。结果表明:对受抑制黄铜矿而言,仅使用丁基黄药就能较好地恢复其可浮性,回收率可达到91.01%,而硫酸铜活化和双氧水氧化对进一步提高可浮性作用较小;受抑制的黄铁矿较黄铜矿更难恢复可浮性,需要经双氧水氧化,然后添加丁基黄药才能使其可浮性有效提高,回收率可达90.22%;受抑制闪锌矿的可浮性最难恢复,而且无论双氧水氧化还是硫酸铜活化均难以恢复其可浮性,其回收率仅不到10%。
中文关键词: 巯基乙酸钠  硫化矿  可浮性  浮选  活化
Abstract:Aiming at the problem that it is difficult to separate and recover copper-zinc sulfide ores after inhibition by sodium thioglycolate, this paper explores the floatability and related mechanism of butyl xanthate, copper sulfate and hydrogen peroxide on these sulfide ores after inhibition by sodium thioglycolate through pure mineral experiments. The results show that for the inhibited chalcopyrite, only the use of butyl xanthate can better restore its floatability, and the recovery rate can reach 91.01 %, while copper sulfate activation and hydrogen peroxide oxidation have little effect on further improving its floatability. The inhibited pyrite is more difficult to recover its floatability than chalcopyrite. It needs to be oxidized by hydrogen peroxide, and then butyl xanthate is added to effectively improve its floatability. The recovery rate can reach 90.22 %. The floatability of the inhibited sphalerite is the most difficult to recover, and it is difficult to recover its floatability regardless of hydrogen peroxide oxidation or copper sulfate activation, and its recovery rate is only less than 10 %.
文章编号:20240209001     中图分类号:    文献标志码:
基金项目:国家自然科学基金51804080
引用文本:
代旺,邓荣东,肖世洁,赵睿祺,李鑫.受巯基乙酸钠抑制的铜锌硫硫化矿可浮性规律研究[J].矿冶,2025,34(1):.

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