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投稿时间:2024-05-24 修订日期:2024-05-29
投稿时间:2024-05-24 修订日期:2024-05-29
中文摘要: 理论计算结果已经证实MAX相Nb2PC机械性能优于其它MAX相,是极具发展潜力的结构材料。但受限于现有含磷MAX相制备过程存在的原料成本高(原料需使用高纯金属、红磷、石墨粉体)、反应器设计复杂(反应需在密闭石英反应器中进行)以及反应时间长(由于磷沸点低,需进行长时间的低温磷化-高温反应制备MAX相)等瓶颈问题,含磷MAX相的深入研究一直被忽视。基于此,本文创新提出了基于气固反应机理的含磷MAX相高温磷化制备新思路,利用生产黄磷副产物磷铁渣中的FeP高温释放磷蒸汽特征,使其在高温下对Nb2O5碳热还原产物NbC进行磷化,成功实现了MAX相Nb2PC的高效制备。同时,探究了原料配比、烧结温度及保温时间对产物纯度的影响。结果表明,当NbC与磷铁渣摩尔比为1:5时,在1200 ℃下保温1 h可得到纯度大于99 %的Nb2PC。该创新方法有望为含磷MAX相的低成本、规模化制备提供技术基础。
Abstract:Theoretical calculations have unequivocally demonstrated that within the MAX phase, Nb2PC showcases superior mechanical properties in comparison to its counterparts, rendering it a profoundly promising material for structural applications. Regrettably, extensive exploration into phosphorus-containing MAX phases has been overlooked due to formidable challenges, including exorbitant raw material expenses (necessitating high-purity metals, red phosphorus, and graphite powders), intricate reactor designs (mandating reactions within sealed quartz reactors), and protracted reaction durations (owing to phosphorus's low boiling point, necessitating a prolonged low-temperature phosphating/high-temperature reaction process for MAX phase synthesis). Drawing from these challenges, this paper introduces an innovative strategy for the high-temperature phosphating synthesis of phosphorus-containing MAX phases, rooted in gas-solid reaction mechanisms. Leveraging the elevated release of phosphorus vapor from FeP in the by-product ferrophosphorus slag during yellow phosphorus production, this method facilitates the phosphating of NbC—a carbon thermal reduction product of Nb2O5—at elevated temperatures, culminating in the successful and efficient production of the Nb2PC MAX phase. Furthermore, the study delves into the influence of raw material ratios, sintering temperature, and duration of thermal retention on product purity. The results indicate that when the molar ratio of NbC to ferrophosphorus slag is 1:5, a purity of greater than 99% of Nb2PC can be obtained by holding at 1200 ℃ for 1 hour. This pioneering approach holds great promise in establishing a technical foundation for the cost-effective and large-scale fabrication of phosphorus-containing MAX phases.
文章编号:20240524002 中图分类号:TF83;TF84; 文献标志码:
基金项目:国家自然科学基金项目(面上项目,重点项目,重大项目)
作者 | 单位 | |
丛良伟 | 沈阳工业大学 | 15141031275@163.com |
庞昇 | 中国科学院过程工程研究所 | spang@ipe.ac.cn |
王志 | 中国科学院过程工程研究所 | zwang@ipe.ac.cn |
李来时* | 沈阳工业大学 | lilaishi@sut.edu.cn |
吴玉胜 | 沈阳工业大学 | wuyus@sut.edu.cn |
引用文本:
丛良伟,庞昇,王志,李来时,吴玉胜.碳化铌高温磷化制备MAX相Nb2PC[J].矿冶,2025,34(1):.
丛良伟,庞昇,王志,李来时,吴玉胜.碳化铌高温磷化制备MAX相Nb2PC[J].矿冶,2025,34(1):.