Study on pre-treatment process of arsenic removal for bismuth-rich lead anode slime
Received:November 27, 2014   Revised:December 03, 2014   Accepted:December 04, 2014      Published Online:December 29, 2015
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KeyWord:bismuth-rich lead anode slime; roasting;alkali leaching; arsenic removal
              
AuthorInstitution
LI Kuo State Key Laboratory of Complex Nonferrous Metal Resources Cleaning Utilization
XU Rui-dong State Key Laboratory of Complex Nonferrous Metal Resources Cleaning Utilization
HE Shi wei kunming university of science and technology
CHEN Han sen kunming university of science and technology
ZHU Yun kunming university of science and technology
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Abstract:
      Abstract: Sodium carbonate roasting and alkali leaching process was used to remove arsenic from bismuth-rich lead anode slime. The effect of those factors including roasting temperature, ratio of liquid to solid, Na2CO3 dosage, oxidant dosage and NaOH concentration on arsenic removal were investigated, and the optimal process conditions were determined. The results show that the leaching rate of arsenic can reach 95% under these conditions of roasting temperature 400℃, liquid-solid ratio 5:1, Na2CO3 dosage 40%, oxidant dosage 10% and NaOH concentration 120g/L. The cyclic utilization of alkaline leaching solution and removal of arsenic can be realized through the method that, filtering crystals after cooling alkaline leaching solution; finally, return such solution to leaching process after adding quantitative sodium hydroxide.
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