Study on the recovery of vanadium and molybdenum from the spent catalyst
Received:June 08, 2018   Revised:June 08, 2018   Accepted:June 13, 2018      Published Online:May 13, 2019
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KeyWord:spent catalyst; vanadium; molybdenum; alkaline roasting; water leaching
              
AuthorInstitution
MA Zhiyuan Guangdong Institute of Resources Comprehensive Utilization,Guangdong Academy of Sciences
LIU Yong Guangdong Institute of Resources Comprehensive Utilization,Guangdong Academy of Sciences
ZHOU Jikui Guangdong Institute of Resources Comprehensive Utilization,Guangdong Academy of Sciences
LIU Mudan Guangdong Institute of Resources Comprehensive Utilization,Guangdong Academy of Sciences
LIU Zhenzhen Guangdong Institute of Resources Comprehensive Utilization,Guangdong Academy of Sciences
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Abstract:
      The study of alkaline roasting-water leaching of the spent catalyst containing vanadium and molybdenum has been investigated. The results showed that the optimized parameters of the alkaline roasting-water leaching are as follow: roasting temperature of 700°C, addition of Na2CO3 of 40%(mNa2CO3/(mNa2CO3 mraw ore), roasting time of 120 min, leaching temperature of 90°C, solid-liquid ratio of 0.20 g.mL-1, leaching time of 90 min and stirring speed of 400 r.min-1. The comparative experimental study of three different methods (alkaline roasting-water leaching, oxidizing roasting-alkaline leaching and atmospheric pressure alkaline leaching) has been investigated. The best method of treatment of the spent catalyst containing vanadium and molybdenum is the process of alkaline roasting-water leaching. The recoveries of vanadium and molybdenum are 97.61% and 97.33%, respectively.
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