Process study on comprehensive recovery and utilizationSof the CIGS Scrap
Received:November 29, 2018   Revised:January 07, 2019   Accepted:January 11, 2019      Published Online:August 26, 2019
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KeyWord:Selenium;Distillation, Water;Leaching, Extraction, Gallium;Neutralization Precipitation, Alkali;Leaching
                 
AuthorInstitution
Li Sheng-chun Hanergy New Material Technology Co Ltd
Wang Wei-zhen BGRIMM Technology Group
Pan Yong-jin Hanergy New Material Technology Co Ltd
Jin Ran-gong BGRIMM Technology Group
Chang Yao-chao BGRIMM Technology Group
Huang Hai-hui BGRIMM Technology Group
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Abstract:
      The selenium, copper, indium and gallium were comprehensive recovered from the CIGS Scrap by the process which includes sulfatizing roasting, water leaching, copper extraction, indium extraction, gallium neutralization precipitation and alkali leaching. The crude selenium, cathode copper, refined indium and metallic gallium were obtained in the process. The selenium volatilization rate is 99.5% in the Selenium Distillation process under the optimum conditions. The extractions of copper and indium in the solvent extraction are 98.4% and 99.9%, respectively. The leaching rate of gallium can reach 99.5% in the process of gallium neutralization precipitation-alkali leaching.
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